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Seong Won Kim 1 Article
Phase Evolution and Thermal Conductivities of (La1-xGdx)2Zr2O7 Oxides for Thermal Barrier Coatings
Chang-Sup Kwon, Sung-Min Lee, Yoon-Suk Oh, Hyung-Tae Kim, Byung-Koog Jang, Seong Won Kim
J Korean Powder Metall Inst. 2012;19(6):429-434.
DOI: https://doi.org/10.4150/KPMI.2012.19.6.429
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With increase in operating temperature of gas turbine for higher efficiency, it is necessary to find new materials of TBC for replacement of YSZ. Among candidate materials for future TBCs, zirconate-based oxides with pyrochlore and fluorite are prevailing ones. In this study, phase structure and thermal conductivities of (La_1-xGd_x)_2Zr_2O_7 oxide system are investigated. (La_1-xGd_x)_2Zr_2O_7 system are comprised by selecting La3+/Gd3+ as A-site ions and Zr4+ as B-site ion in A_2B_2O_7 pyrochlore structures. With powder mixture from each oxide, (La_1-xGd_x)_2Zr_2O_7 oxides are fabricated via solid-state reaction at 1600°C. Either pyrochlore or fluorite or mixture of both appears after heat treatment. For the developed phases along (La_1-xGd_x)_2Zr_2O_7 compositions, thermal conductivities are examined, with which the potential of (La_1-xGd_x)_2Zr_2O_7 compositions for TBC application is also discussed.

Citations

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  • Fabrication and Characterization of Ceramics and Thermal Barrier Coatings of Lanthanum Zirconate with Reduced Rare-earth Contents in the La2O3-ZrO2 System
    Chang-Sup Kwon, Sujin Lee, Sung-Min Lee, Yoon-Suk Oh, Hyung-Tae Kim, Byung-Koog Jang, Seongwon Kim
    Journal of Korean Powder Metallurgy Institute.2015; 22(6): 413.     CrossRef
  • Preparation of Suspension in La2O3-Gd2O3-ZrO2System via Planetary Mill and Characteristics of (La1-xGdx)2Zr2O7Coatings Fabricated via Suspension Plasma Spray
    Chang-Sup Kwon, Sung-Min Lee, Yoon-Suk Oh, Hyung-Tae Kim, Byung-Koog Jang, Seongwon Kim
    Journal of Korean Powder Metallurgy Institute.2013; 20(6): 453.     CrossRef
  • Fabrication and Characteristics of Yttria-stabilized Zirconia (7.5 wt% Y2O3-ZrO2) Coating Deposited via Suspension Plasma Spray
    Won-Jun Lee, Chang-Sup Kwon, Seongwon Kim, Yoon-Suk Oh, Hyung-Tae Kim, Dae-Soon Lim
    Journal of Korean Powder Metallurgy Institute.2013; 20(6): 445.     CrossRef

Journal of Powder Materials : Journal of Powder Materials